Surface Science

Foundations of Catalysis and Nanoscience

Kurt W. Kolasinski

304 pages, parution le 05/02/2002

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Résumé

Offering a broad introduction to surface chemistry, this book covers both traditional topics such as adsorption, desorption, and reactions between adsorbates, as well as reactions involved in growth. Readers will gain a firm understanding of how chemistry works at surfaces as well as comprehend and probe the dynamics of surface reactions.

Contents

Introduction

1. Surface Structure

Clean surface structure
Reconstruction and adsorbate structure
Band structure of solids
The vibration of solids
Summary of important concepts

2. Experimental probes of surface and adsorbate structure

Scanning probe techniques
Low-energy electron diffraction
Electron spectroscopy
Vibrational spectroscopy
Other surface analytical techniques
Summary of important concepts

3. Chemisorption, physisorption and dynamics

Types of interactions
Binding sites and diffusion
Physisorption
Nondissociative chemisorption
Dissociative chemisorption: H2 on a simple metal
What determines the reactivity of metals?
Atoms and molecules incident on a surface
Microscopic reversibility in ad/desorption phenomena
The influence of individual degrees of freedom on adsorption and desorption
Translations, corrugation and surface atom motions
Rotations and adsorption
Vibrations and adsorption
Competitive adsorption and collision-induced processes
Classification of reaction mechanisms
Measurment of sticking coefficients
Summary of important concepts

4. Thermodynamics and kinetics of surface processes

Thermodynamics of ad/desorption
Adsorption isotherms: thermodynamics approach
Lateral interactions
Rate of desorption
Kinetics of adsorption
Adsorption isotherms: kinetics approach
Temperature-programmed desorption
Summary of important concepts

5. Complex surface reactions: catalysis and etching

Measurement of surface kinetics and reaction mechanisms
Haber-Bosch process
From microscopic kinetics to catalysis
Fischer-Tropsch synthesis and relatedchemistry
The threeway automotive catalyst
Promoters
Poisons
Rate oscillations and spatiotemporal pattern formation
Etching
Summary of important concepts

6. Growth and epitaxy

Stress and strain
Types of interfaces
Surface energy and surface tension
Growth modes
Growth away from equilibrium
Techniques for growing layers
Langmuir films
Langmuir-Blodgett films
Self-assembled monolayers
Summary of important concepts

Appendices
Index

Caractéristiques techniques

	PAPIER
Éditeur(s)	Wiley
Auteur(s)	Kurt W. Kolasinski
Parution	05/02/2002
Nb. de pages	304
Format	16,8 x 24,4
Couverture	Broché
Poids	626g
Intérieur	Noir et Blanc
EAN13	9780471492450
ISBN13	978-0-471-49245-0

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Surface Science

Résumé

Caractéristiques techniques

Nouveautés "Physique des surfaces"

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