The Organometallic Chemistry of the Transition Metals

Robert H. Crabtree - Collection Wiley-Interscience

546 pages, parution le 01/08/2005 (4^eme édition)

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Résumé

There have been a number of notable advances in the field of organometallic chemistry over the past decade. Transition metal organometallic chemistry has provided researchers-especially those working in the Pharmaceuticals, natural product synthesis, and polymer industries-with powerful new synthetic tools, and the field has expanded to include life science aspects, such as metalloenzymes involving organometallic intermediates and nanotechnology, such as nanopar-ticles and giant molecules.

Fully updated and expanded to reflect recent advances, this Fourth Edition of the classic text provides students and professional chemists with a comprehensive introduction to the principles and general properties of organometallic compounds. It also supplies a wealth of practical information about relevant reaction mechanisms, along with detailed descriptions of contemporary applications to organic synthesis, organized by reaction type. Additionally, the numerous references to pertinent literature, found throughout the text, will be appreciated by students and professional chemists alike.

New to this edition are:

A new section on elements of the f-block and expanded coverage of paramagnetic organometallic compounds
Extensive revisions to the chapter on organic synthetic applications including new sections on coupling, metathesis, nucleophilic substitution, Lewis acid reactions, chiral bases, and other catalytic reactions
Significant updates to the chapter on bioorganometallic chemistry, including hydro-genase, acetyl CoA synthase, and methyl CoM reductase, as well as a discussion of biomedical applications
Bibiliographic references to many useful reviews

The Organometallic Chemistry oftheTransition Metals, Fourth Edition is an unparalleled pedagogic resource, appropriate as a main text for courses in inorganic chemistry and organometallic chemistry, and as a supplementary text for courses in bioinorganic chemistry. It is also a valuable working reference for professional chemists who need to become better acquainted with the subject.

L'auteur - Robert H. Crabtree

Robert H. Crabtree, PhD, is a professor in the Department of Chemistry at Yale University. He has served on the editorial boards of Chemical Reviews, New Journal of Chemistry, Journal of Molecular Catalysis, and Organometallics and has received numerous awards for his research accomplishments including the Organometallic Chemistry Prize of the Royal Society of Chemistry (1991) and the Organometallic Chemistry Prize of the American Chemical Society (1993).

Sommaire

Preface
List of Abbreviations
Introduction
General Properties of Organometallic Complexes
Metal Aryls, and Hybrides and Related σ-Bonded Ligands
Carbonyls, Phosphine Complexes, and Ligand Substitution Reactions
Complexes of π-Bounds Ligands
Oxidative Addition and Reductive Elimination
Insertion and Elimination
Nucleophilic and Electrophilic Addition and Abstraction
Homogeneous Catalysis
Physical Methods in Organometallic Chemistry
Metal-Ligand Multiple Bonds
Applications of Organometallic Chemistry
Clusters and the Metal-Metal Bond
Applications to Organic Synthesis
Paramagnetic, High-Oxidation-State, and High-Coordination-Number Complexes
Bioorganometallic Chemistry
Useful Texts on Allied Topics
Major Reaction Types
Solutions to Problems
Index

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	PAPIER
Éditeur(s)	Wiley
Auteur(s)	Robert H. Crabtree
Collection	Wiley-Interscience
Parution	01/08/2005
Édition	4^eme édition
Nb. de pages	546
Format	16 x 24
Couverture	Relié
Poids	870g
Intérieur	Noir et Blanc
EAN13	9780471662563
ISBN13	978-0-471-66256-3