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Silicon chemistry
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Silicon chemistry

Silicon chemistry

From the atom to extended systems

Peter Jutzi, Ulrich Schubert, Collectif Wiley

506 pages, parution le 17/10/2003

Résumé

The combined results from an international research project involving 40 interdisciplinary groups, providing the latest knowledge from the past few years. Adopting an application-oriented approach, this handy reference is a must-have for every silicon chemist, whether working in inorganic, organic, physical or polymer chemistry, materials science or physics.

Contents

  • Reactive Intermediates in Silicon Chemistry - Synthesis, Characterization, and Kinetic Stabilization
    • Introduction
    • Investigations on the Reactivity of Atomic Silicon
    • Reactions with Matrix Isolated SiO Molecules
    • In situ - Diagnostics of Amorphous Silicon Thin Film Deposition
    • The Gas Phase Oxidation of Silyl Radicals by Molecular Oxygen
    • Oxidation of Matrix-Isolated Silylenes
    • Short-Lived Intermediates with Double Bonds to Silicon
    • Kinetic Stabilization of Disilenes
    • A Tetrasilabuta-1,3-diene and Related Compounds with Conjugated Multiple Bonds
  • SI-SI-Systems : From Molecular Building Blocks to Extended Networks
    • Introduction
    • Chemistry of Metalated Oligosilanes
    • Oligosilyl Substituted Heptaphosphanes
    • Polysilanes: Formation, Bonding and Structure
    • Phase Behavior of n-Alkylsubstituted Polysilanes
    • Structural and Electronic Systematics in Zintl Phases of the Tetrels
    • Zintl Phases MSi2 ( M = Ca, Eu, Sr, Ba) at Very High Pressure
    • Silicon- and Germanium-Based Sheet Polymers and Zintl Phases
    • Kautsky-Siloxene Analogous Monomers and Oligomers
    • Silicon-Based Nanotubes
    • Structure and Reactivity of Solid SiO
    • Si Nanocrystallites in SiOx Films by Vapour Deposition and Thermal Processing
    • Theoretical Treatment of Silicon Clusters
    • Isomers of Neutral Silicon Clusters
    • Investigation of the Influence of Oxidation and HF Attack on the Photoluminescence of Silicon Nanoparticles
    • Localization Phenomena and Photoluminscence from Nano-structured Silicon, Silicon/Silicon Dioxide. Nanocomposites, Silsesquioxanes and Branched Polysilanes
  • SI-O Systems : From Molecular Building Blocks to Extended Networks
    • Introduction
    • Higher-Coordinate Silicon Compounds with SiO5 and SiO6 Skeletons
    • Functionalized Silanols and Silanolates
    • Transition Metal Fragment Substituted Silanols of Iron and Tungsten - Synthesis, Structure and Condensation Reactions
    • Rational Syntheses of Cyclosiloxanes and Molecular Alumo- and Gallosiloxanes
    • Synthesis, Structure and Reactivity of Novel Oligomeric Titanasiloxanes
    • Metallasilsesquioxanes
    • Spin-Spin Interaction in Silsesquioxanes and Transition Metal Substitution
    • Characterization of Si-polymers by Coupling of HPLC-Separation Methods with MALDI-TOF-MS
    • The Stepwise Formation of Si-O-Networks
    • Mechanism of Ring and Cage Formation in Siloxanes
    • Structurally Well-Defined Amphiphilic Polysiloxane Copolymers
    • Synthesis and Functionalization of Mesostructured Silica-Based Films
    • Modification of Ordered Mesostructured Materials during Synthesis
    • Biosilicification; Structure, Regulation of Structure and Model Studies
  • Subject Index

L'auteur - Collectif Wiley

Collectif Wiley

Caractéristiques techniques

  PAPIER
Éditeur(s) Wiley
Auteur(s) Peter Jutzi, Ulrich Schubert, Collectif Wiley
Parution 17/10/2003
Nb. de pages 506
Format 17,5 x 24,5
Couverture Relié
Poids 1105g
Intérieur Noir et Blanc
EAN13 9783527306473

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